Mixed oxides with corundum-type structure obtained from recycling can seals as paint pigments: color stability

• Dienifer F. L. Horsth,
• Julia de O. Primo,
• Nayara Balaba,
• Fauze J. Anaissi and
• Carla Bittencourt

Beilstein J. Nanotechnol. 2023, 14, 467–477, doi:10.3762/bjnano.14.37

• and color can be adjusted by the calcination temperature or the combination with other metals as coloring ions [11]. In this context, applying both Cr and Fe ions as coloring ions in a white matrix such as aluminium oxide is interesting. We report on the synthesis of synthetic inorganic pigments using

• environments. In the case of mixed chromium/aluminium oxide, the highest concentration of coloring ions provided the highest color stability (Table S2, Supporting Information File 1). Similar behavior was observed for samples with Fe. In general, 20 wt % of coloring ions led to better color stability in

Experimental and theoretical study of field-dependent spin splitting at ferromagnetic insulator–superconductor interfaces

• Peter Machon,
• Michael J. Wolf,
• Detlef Beckmann and
• Wolfgang Belzig

Beilstein J. Nanotechnol. 2022, 13, 682–688, doi:10.3762/bjnano.13.60

• a Si(111) substrate heated to 800 °C. In a second fabrication step, aluminium/aluminium oxide/copper tunnel junctions were fabricated on the EuS film using e-beam lithography and shadow evaporation. The nominal aluminium film thickness was d = 10 nm. The differential conductance g = dI/dV of the

Plasmon-enhanced photoluminescence from TiO₂ and TeO₂ thin films doped by Eu³⁺ for optoelectronic applications

• Marcin Łapiński,
• Jakub Czubek,
• Katarzyna Drozdowska,
• Anna Synak,
• Wojciech Sadowski and
• Barbara Kościelska

Beilstein J. Nanotechnol. 2021, 12, 1271–1278, doi:10.3762/bjnano.12.94

• platforms show an increased intensity of the excitation peak. Moreover, samples with an additional aluminium oxide ultrathin film exhibit a higher excitation intensity. The increased excitation for samples with Au nanostructures may be ascribed to the plasmonic resonance effect, which results in greater

Uniform arrays of gold nanoelectrodes with tuneable recess depth

• Elena O. Gordeeva,
• Ilya V. Roslyakov,
• Alexey P. Leontiev,
• Alexey A. Klimenko and
• Kirill S. Napolskii

Beilstein J. Nanotechnol. 2021, 12, 957–964, doi:10.3762/bjnano.12.72

• alternative approach includes bulk electrode structuring by deposition or etching techniques using self-assembled arrays of colloidal nanoparticles [15], liquid crystals [16], or track-etched membranes [17][18][19] as template or mask, respectively. Among porous templates, anodic aluminium oxide (AAO) allows

9.1% efficient zinc oxide/silicon solar cells on a 50 μm thick Si absorber

• Rafal Pietruszka,
• Bartlomiej S. Witkowski,
• Monika Ozga,
• Katarzyna Gwozdz,
• Ewa Placzek-Popko and
• Marek Godlewski

Beilstein J. Nanotechnol. 2021, 12, 766–774, doi:10.3762/bjnano.12.60

• research groups. This technology was invented in the 1970s by Tuomo Suntola from Finland [4]. Thanks to the unique properties of this technology, materials produced by ALD quickly found a number of applications in PV. For example, ultrathin films of aluminium oxide (Al2O3) are used to passivate silicon

Atomic layer deposited films of Al₂O₃ on fluorine-doped tin oxide electrodes: stability and barrier properties

• Hana Krýsová,
• Michael Neumann-Spallart,
• Hana Tarábková,
• Pavel Janda,
• Ladislav Kavan and
• Josef Krýsa

Beilstein J. Nanotechnol. 2021, 12, 24–34, doi:10.3762/bjnano.12.2

• semiconducting electrodes, such as ZnO. Aluminium oxide is another promising candidate for this task. It is amphoteric but insoluble in aqueous media at a neutral pH value [8][9]. ALD oxide layers, including Al2O3, were used as barrier coatings on copper to protect against corrosion in 0.1 M NaCl [10]. As

• precursor was 0.1 s with a purge time of 5 s and the pulse of H2O was 0.1 s with a purge time of 10 s. TMA and water were maintained at 22 °C. Nitrogen (99.999%, Linde) was used as a carrier gas. The deposition of aluminium oxide films on silicon or FTO was carried out by performing 30, 60, 120, and 200

• FTO coated with a 17 nm Al2O3 layer were practically the same (i.e., 35 and 34 nm, respectively). This shows that Al2O3 was conformally deposited onto the FTO surface. Next, the blocking properties of the aluminium oxide layers were tested via cyclic voltammetry on ALD-deposited Al2O3 films of various

A set of empirical equations describing the observed colours of metal–anodic aluminium oxide–Al nanostructures

• Cristina V. Manzano,
• Jakob J. Schwiedrzik,
• Gerhard Bürki,
• Laszlo Pethö,
• Johann Michler and
• Laetitia Philippe

Beilstein J. Nanotechnol. 2020, 11, 798–806, doi:10.3762/bjnano.11.64

• .11.64 Abstract Structural colours have received a lot of attention regarding the reproduction of the vivid colours found in nature. In this study, metal–anodic aluminium oxide (AAO)–Al nanostructures were deposited using a two-step anodization and sputtering process to produce self-ordered anodic

• aluminium oxide films and a metal layer (8 nm Cr and 25, 17.5 and 10 nm of Au), respectively. AAO films of different thickness were anodized and the Yxy values (Y is the luminance value, and x and y are the chromaticity values) were obtained via reflectance measurements. An empirical model based on the

• thickness and porosity of the nanostructures was determined, which describes a gamut of colours. The proposed mathematical model can be applied in different fields, such as wavelength absorbers, RGB (red, green, blue) display devices, as well as chemical or optical sensors. Keywords: anodic aluminium oxide

Self-assembly of a terbium(III) 1D coordination polymer on mica

• Quentin Evrard,
• Giuseppe Cucinotta,
• Felix Houard,
• Guillaume Calvez,
• Yan Suffren,
• Carole Daiguebonne,
• Olivier Guillou,
• Andrea Caneschi,
• Matteo Mannini and
• Kevin Bernot

Beilstein J. Nanotechnol. 2019, 10, 2440–2448, doi:10.3762/bjnano.10.234

• on the mica surface that can lead to the formation of potassium carbonate (K2CO3) when mica is air-cleaved. Recent findings [32][33][34][35] show that the mechanism of K+ depletion from air-cleaved mica is not fully known but resembles the one observed on aluminium oxide [36], iron oxide [37] or

A biomimetic nanofluidic diode based on surface-modified polymeric carbon nitride nanotubes

• Kai Xiao,
• Baris Kumru,
• Lu Chen,
• Lei Jiang,
• Bernhard V. K. J. Schmidt and
• Markus Antonietti

Beilstein J. Nanotechnol. 2019, 10, 1316–1323, doi:10.3762/bjnano.10.130

• systems and the generation of blue energy from salinity gradients [23][24]. We fabricated a carbon nitride nanotube membrane (CNNM) via an anodic aluminium oxide (AAO)-templated vapor deposition–polymerization process. Subsequently, the CNNMs were modified with 3-allyloxy-2-hydroxy-1-propanesulfonic acid

Photoactive nanoarchitectures based on clays incorporating TiO₂ and ZnO nanoparticles

• Eduardo Ruiz-Hitzky,
• Pilar Aranda,
• Marwa Akkari,
• Nithima Khaorapapong and
• Makoto Ogawa

Beilstein J. Nanotechnol. 2019, 10, 1140–1156, doi:10.3762/bjnano.10.114

• ), montmorillonite (B), sepiolite (C), halloysite nanotubes (HNT) (D), and the metal oxides, anatase (E) and wurtzite (F), obtained by applying the VESTA software using the following color codes: silicon oxide tetrahedron – blue: Si, red: O. In kaolinite and halloysite – aluminium oxide-hydroxide octahedron: green

Ceria/polymer nanocontainers for high-performance encapsulation of fluorophores

• Kartheek Katta,
• Dmitry Busko,
• Yuri Avlasevich,
• Katharina Landfester,
• Stanislav Baluschev and
• Rafael Muñoz-Espí

Beilstein J. Nanotechnol. 2019, 10, 522–530, doi:10.3762/bjnano.10.53

• , Alfa Aesar, 99%), and 2,2'-azobis(2-methylbutyronitrile) (V59, Wako) were used as received. Styrene was passed over an aluminium oxide column to remove the stabilizer before use. Synthesis of the dye and preparation of its stock solution N,N’-(2,6-Diisopropylphenyl)-1,6,9,13-tetrakis[4-(1,1,3,3

Friction reduction through biologically inspired scale-like laser surface textures

• Johannes Schneider,
• Vergil Djamiykov and
• Christian Greiner

Beilstein J. Nanotechnol. 2018, 9, 2561–2572, doi:10.3762/bjnano.9.238

• . Aluminium oxide is a common material in those investigations [35][36]. Therefore, and because Al2O3 can be considered as the model engineering ceramic, it was chosen as the counter body material for testing the performance of the scale-like surface morphology in a steel-on-ceramic contact. The results of

• friction coefficient for the steel-on-ceramic contact are significantly larger compared to the steel and polymer counter bodies presented above. This might be due to the significantly larger surface roughness of the aluminium oxide discs compared to the PEEK and 100Cr6 ones. Unfortunately, it is

• third counter body material tested was aluminium oxide (FRIALIT F99,7), purchased from FRIATEC AG (Mannheim, Germany). The roughness of these discs after grinding was Ra = 0.65 ± 0.1 µm. The Young’s modulus was determined to be 384 GPa and the hardness was measured as 1670 HV1. For the experiments

Increasing the stability of DNA nanostructure templates by atomic layer deposition of Al₂O₃ and its application in imprinting lithography

• Hyojeong Kim,
• Kristin Arbutina,
• Anqin Xu and
• Haitao Liu

Beilstein J. Nanotechnol. 2017, 8, 2363–2375, doi:10.3762/bjnano.8.236

• resistive to UV/O3 oxidation. The ALD-coated DNA templates were used for a direct pattern transfer to poly(L-lactic acid) films. Keywords: aluminium oxide (Al2O3); atomic layer deposition; DNA nanostructure; nanofabrication; nanoimprint lithography; pattern transfer; polymer stamp; replica molding

Synthesis of coaxial nanotubes of polyaniline and poly(hydroxyethyl methacrylate) by oxidative/initiated chemical vapor deposition

• Alper Balkan,
• Efe Armagan and
• Gozde Ozaydin Ince

Beilstein J. Nanotechnol. 2017, 8, 872–882, doi:10.3762/bjnano.8.89

• temperature (25–100 °C), adequate electrical conductivity for a wide range of applications and high-quality conformal CP thin films on various non-planar surfaces [39][40][41]. In this study, the vapor-phase oCVD and iCVD techniques were used to conformally coat the walls of the pores of anodized aluminium

• oxide (AAO) track-etch membranes. The ability to control the thickness with high sensitivity using these vapor phase techniques allowed to produce coaxial nanotubes. The response of these nanotubes to the changes in humidity could be tuned by introducing the hydrogel inner layer. Results and Discussion

Liquid permeation and chemical stability of anodic alumina membranes

• Dmitrii I. Petukhov,
• Dmitrii A. Buldakov,
• Alexey A. Tishkin,
• Alexey V. Lukashin and
• Andrei A. Eliseev

Beilstein J. Nanotechnol. 2017, 8, 561–570, doi:10.3762/bjnano.8.60

• -soluble alumina species to the permeate side of membrane during water filtration, encouraging possible blockage of channels. The effect is strongly enhanced by a slight gradient of pH within the pore due to the neutralization reaction by dissolved aluminium oxide. The physical blockage of AAO nanochannels

When the going gets rough – studying the effect of surface roughness on the adhesive abilities of tree frogs

• Niall Crawford,
• Thomas Endlein,
• Jonathan T. Pham,
• Mathis Riehle and
• W. Jon P. Barnes

Beilstein J. Nanotechnol. 2016, 7, 2116–2131, doi:10.3762/bjnano.7.201

• topographic features (random asperities and regular patterns). For whole animal tilting experiments, the rough surfaces (35 × 21 cm) used consisted of eight different grades of polishing discs and sandpaper (made from Aluminium oxide) from multiple sources (3M, USA; Norton abrasives, France; Ultratec, USA), a

Distribution of Pd clusters on ultrathin, epitaxial TiO_x films on Pt₃Ti(111)

• Christian Breinlich,
• Maria Buchholz,
• Marco Moors,
• Tobias Pertram,
• Conrad Becker and
• Klaus Wandelt

Beilstein J. Nanotechnol. 2015, 6, 2007–2014, doi:10.3762/bjnano.6.204

• the Moiré superstructure of ultrathin aluminium oxide films grown on the chemically ordered, Ni3Al(111) surface [11][12][13][14]. The advantages of growing an oxide film from a component of an ordered alloy surface with a higher enthalpy of oxide formation are the somewhat better structural quality of

Nanomechanical humidity detection through porous alumina cantilevers

• Olga Boytsova,
• Alexey Klimenko,
• Vasiliy Lebedev,
• Alexey Lukashin and
• Andrey Eliseev

Beilstein J. Nanotechnol. 2015, 6, 1332–1337, doi:10.3762/bjnano.6.137

• behavior of the resonance frequency of porous anodic alumina cantilever arrays during water vapor adsorption and emphasize their possible use in the micromechanical sensing of humidity levels at least in the range of 10–22%. The sensitivity of porous anodic aluminium oxide cantilevers (Δf/Δm) and the

• of the cantilever arrays for micromechanical sensing. Keywords: anodic aluminium oxide; atomic force microscopy (AFM); cantilever arrays; humidity; mechanical sensor; porous alumina; Introduction The last two decades have seen a surge in resonant micro- and nanomechanical engineering raised by the

• through porosity”. One promising porous system exhibiting all the necessary characteristics is anodic aluminium oxide (AAO). Its huge surface area offers an enormous number of binding sites. The adsorption of chemicals on the surface of the cantilever manifests itself by the shift of the resonance

Silica micro/nanospheres for theranostics: from bimodal MRI and fluorescent imaging probes to cancer therapy

• Shanka Walia and
• Amitabha Acharya

Beilstein J. Nanotechnol. 2015, 6, 546–558, doi:10.3762/bjnano.6.57

• deposition of a silica layer on aluminium oxide and then to this solution trimethoxy(octadecyl)silane (C18-silane) was added. Next, to this silica microemulsion mixture the fluorescent material rhodamine B (RhB) was added. Finally, Fe3O4 NPs were introduced inside gold-capped nanotubes. The structure and

Filling of carbon nanotubes and nanofibres

• Reece D. Gately and
• Marc in het Panhuis

Beilstein J. Nanotechnol. 2015, 6, 508–516, doi:10.3762/bjnano.6.53

• surface or alters their morphology in undesired ways (e.g., reduction in length). Due to this challenge, much research has been focussed on producing CNTs that are open at both ends. This has been achieved by using an anodic aluminium oxide (AAO) film as a template for the thermal decomposition of

Advances in NO₂ sensing with individual single-walled carbon nanotube transistors

• Kiran Chikkadi,
• Matthias Muoth,
• Cosmin Roman,
• Miroslav Haluska and
• Christofer Hierold

Beilstein J. Nanotechnol. 2014, 5, 2179–2191, doi:10.3762/bjnano.5.227

• later be removed selectively, it is possible to improve the contact resistance as well as reduce the hysteresis simultaneously, as shown by Khamis et al. [66] with organic layers, and Liu et al. [17] with an aluminium oxide layer. Another possibility is to eliminate dielectrics altogether, for example

Nanostructure sensitization of transition metal oxides for visible-light photocatalysis

• Hongjun Chen and
• Lianzhou Wang

Beilstein J. Nanotechnol. 2014, 5, 696–710, doi:10.3762/bjnano.5.82

• nanocrystal by micro-emulsion under ultrasound [57]. Co-axial arrays of CdS/TiO2 core/shell structures were also reported to be fabricated by an anodic aluminium oxide template [58]. This type of configuration can not only protect the quantum dots from photocorrosion, but also increases the contact interface

Preparation of electrochemically active silicon nanotubes in highly ordered arrays

• Tobias Grünzel,
• Young Joo Lee,
• Karsten Kuepper and
• Julien Bachmann

Beilstein J. Nanotechnol. 2013, 4, 655–664, doi:10.3762/bjnano.4.73

• SiO2 coating only reaches a depth on the order of 10 µm. Note that the maximal depth of the deposit could be increased by larger pore diameters and/or optimized experimental conditions [19][20]. The uncoated depth of the aluminium oxide matrix remains chemically and electrochemically inert, and thus

Grain boundaries and coincidence site lattices in the corneal nanonipple structure of the Mourning Cloak butterfly

• Ken C. Lee and
• Uwe Erb

Beilstein J. Nanotechnol. 2013, 4, 292–299, doi:10.3762/bjnano.4.32

• effect, which provides some protection from predators. In recent years many artificial moth-eye-type surfaces have been developed as antireflection, antiglare surfaces by various methods such as photoresist patterning, porous aluminium oxide templating or direct reproduction, e.g., [7][8][9]. With

Sub-10 nm colloidal lithography for circuit-integrated spin-photo-electronic devices

• Adrian Iovan,
• Marco Fischer,
• Roberto Lo Conte and
• Vladislav Korenivski

Beilstein J. Nanotechnol. 2012, 3, 884–892, doi:10.3762/bjnano.3.98

• -porous anodic aluminium oxide [19] were shown to scale to sub-10 nm dimensions and potentially compete with the above advanced lithographic techniques at this scale. Another potential alternative for sub-10 nm patterning is colloidal lithography, which is very attractive at larger dimensions due to its